Organic-Inorganic Hybrid Compounds Based on Lead Halide Units: Preparation from Melts and through Grinding Effects
نویسندگان
چکیده
Organic-inorganic hybrid compounds based on lead halide units of the formula (CH3NH3)2(CH3C6H4CH2NH3)2Pb3(BrxY1−x)10 (Y = Cl, I) were prepared from melts, and their optical absorption as well as photoluminescence spectra, before and after grinding the compounds, were investigated. The luminescence of the materials after grinding is strong and is observed with naked eye. By changing the mole fraction (x), the strong photoluminescence in the range from ca. 400 nm to ca. 600 nm could be tuned. These effects indicate that the hybrid compounds are promising materials for potential applications.
منابع مشابه
Giant photostriction in organic-inorganic lead halide perovskites.
Among the many materials investigated for next-generation photovoltaic cells, organic-inorganic lead halide perovskites have demonstrated great potential thanks to their high power conversion efficiency and solution processability. Within a short period of about 5 years, the efficiency of solar cells based on these materials has increased dramatically from 3.8 to over 20%. Despite the tremendou...
متن کاملSome Organic-Inorganic Hybrid Compounds Based on «ö-Thiuronium Cations and Lead Halide Anions
Z. Naturforsch. 56 b, 57-61 (2001); received September 11, 2000 Organic-Inorganic Hybrids, Low-Dimensional Semiconductors, Fluorescence Using 1-chlorodecane (C10H21CI), benzyl chloride (C6H5CH2CI), a,a'-dichloro-p-xylene (CICH2C6H4CH2CI), 4-phenylbenzyl chloride (C6H5C6H4CH2CI), 2-bromomethyl-naphthalene (CioHyC^Br), 4-bromomethyl-7-methoxycoumarin (CioHzO^C^Br), 2-bromomethylanthraquinone (CuH...
متن کاملEffect of TiO2 Nanofiber Density on Organic-Inorganic Based Hybrid Solar Cells (RESEARCH NOTE)
Abstract In this work, a comparative study of hybrid solar cells based on P3HT and TiO2 nanofibers was accomplished. Electrospinning, a low cost production method for large area nanofibrous films, was employed to fabricate the organic-inorganic hybrid solar cells based on poly (3-hexylthiophene) and TiO2 nanofibers. The performance of the hybrid solar cells was analyzed for four density levels ...
متن کاملPhotoinduced processes in lead iodide perovskite solid-state solar cells
Organic-inorganic hybrid systems based on lead halide compounds have recently encountered considerable success as light absorbers in solid-state solar cells. Herein we show how fundamental mechanistic processes in mesoporous oxide films impregnated with CH3NH3PbI3 can be investigated by time resolved techniques. In particular, charge separation reactions such as electron injection into the tita...
متن کاملFerroelectric solar cells based on inorganic–organic hybrid perovskites
Ferroelectric solar cells based on ferroelectric oxides have attracted significant attention owing to many unique advantages, such as the switchable photocurrent and photovoltage, and the above bandgap open circuit voltages. However, the small photocurrent densities of the typical ferroelectric solar cells greatly limit their photovoltaic performance. In this report, we experimentally revealed ...
متن کامل